Product ID:27036-9, 1,1,2-TRICHLOROTRIFLUOROETHANE, (SUPDAT)
MSDS Date:02/25/1992
FSC:6850
NIIN:00N015020
MSDS Number: CDKVZ

Emergency Phone: 414-273-3850

Info Phone: 414-273-3850

Cage: 60928

Telephone: 414-273-3850

Cage: 60928

ETHANE, 1,1,2-TRICHLORO-1,2,2-TRIFLUORO-;

CAS: 76-13-1

RTECS: KJ4000000

Fraction By Weight: 99.9%

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM; 1250 STEL

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:CHLOROFLUOROCARBON (CFC) MATERIALS
HAVE PRODUCED SENSITIZATION OF THE MYOCARDIUM TO EPINEPHRINE IN LAB
ANIMALS AND COULD HAVE A SIMILAR EFFECT IN HUMANS. ADRENOMIMETICS
(IE, EPINEPHRINE) MAY BE CONTRA -INDICATED EXCEPT FOR
LIFE-SUSTAINING USES IN HUMANS ACUTELY OR CHRONICALLY EXPOSED TO
CFCS . (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: MAY BE HARMFUL BY INHALATION,
INGESTION OR SKIN ABSORPTION. MAY CAUSE IRRITATION. PROLONGED
EXPOSURE CAN CAUSE NARCOTIC EFFECT.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES: IMMED FLUSH EYES W/COPIOUS AMOUNTS OF WATER FOR AT
LEAST 15 MIN. SKIN: IMMED FLUSH SKIN W/COPIOUS AMOUNTS OF WATER FOR
AT LEAST 15 MIN WHILE REMOVING CONTAMD CLTHG & SHOES. INHAL: REMOVE
TO FRES H AIR. IF NOT BREATHING GIVE ARTIFICIALRESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. INGEST: WASH OUT MOUTH W/WATER
PROVIDED PERSON IS CONSCIOUS. CALL MD. WASH CONTAMD CLTHG BEFORE
REUSE.

Flash Point:NONE
Extinguishing Media:USE EXTINGUISHING MEDIA APPROPRIATE TO SURROUNDING
FIRE CONDITIONS.
Fire Fighting Procedures:WEAR NIOSH APPROVED PRESSURE DEMAND SCBA AND
FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:THERMAL DECOMPOSITION PRODUCTS MAY
INCLUDE FLUORIDES, CHLORIDES AND PHOSGENE . EMITS TOXIC FUMES
UNDER FIRE CONDITIONS.

Spill Release Procedures:EVACUATE AREA. WEAR NIOSH APPROVED
SELF-CONTAINED BREATHING APPARATUS, RUBBER BOOTS & HEAVY RUBBER
GLOVES. ABSORB ON SAND OR VERMICULITE & PLACE IN CLOSED CONTAINERS
FOR DISPOSAL. VENTILATE AREA & WAS H SPILL SITE AFTER MATERIAL
PICKUP IS COMPLETE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DO NOT BREATHE VAPOR. DO NOT GET IN
EYES, ON SKIN, ON CLOTHING. WASH THOROUGHLY AFTER HANDLING. KEEP
TIGHTLY CLOSED. STORE IN A COOL, DRY PLACE.
Other Precautions:NO SMKNG IN AREA OF USE. DO NOT USE IN GEN VICINITY
OF ARC WELDING, OPEN FLAMES OR HOT SURFS. HEAT &/OR UV RADIA MAY
CAUSE THE FORMATION OF CHLORIDES, FLUORIDES OR PHOSGENE . THIS MATL
CAN REACT VIOLENTLY W/ACTIVE METALS SUCH (SUPDAT)

Respiratory Protection:WEAR APPROPRIATE NIOSH APPROVED RESPIRATOR.
Ventilation:MECHANICAL EXHAUST REQUIRED.
Protective Gloves:CHEMICAL-RESISTANT GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
WEAR OTHER PROTECTIVE CLOTHING.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
MFR'S TRADE NAME/PART NO: 99.9+%, HPLC GRADE. VP: 284 @ 20C; 334 @ 25C.
OTHER PRECS: AS SODIUM, POTASSIUM, CALCIUM, BARIUM & W/FINELY
DIVIDED METALS SUCH AS ALUMINUM, MAGNESIUM, ZINC & BERYLLIUM. CONT
ACT W/MAGNESIUM ALLOYS CONTAINING MORE THAN 2% MAGNESIUM MAY CAUSE
DECOMPOSITION.

Boiling Pt:B.P. Text:>117F,>47C
Melt/Freeze Pt:M.P/F.P Text:-31F,-35C
Vapor Pres:SUPDAT
Vapor Density:2.39
Spec Gravity:1.575
Appearance and Odor:COLORLESS LIQUID.

Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:FINELY POWDERED METALS, ALUMINUM,
MAGNESIUM, ZINC, REACTS VIOLENTLY WITH SODIUM, POTASSIUM.
Hazardous Decomposition Products:PHOSGENE . TOXIC FUMES OF: CARBON
MONOXIDE, CARBON DIOXIDE, HYDROGEN CHLORIDE GAS, HYDROGEN FLUORIDE.

Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL,
STATE AND LOCAL REGULATIONS . DISSOLVE OR MIX THE MATERIAL WITH A
COMBUSTIBLE SOLVENT AND BURN IN A CHEMICAL INCINERATOR EQUIPPED
WITH AN AFTERBURNER AND SCRUBBER.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.